Chemical leaching is useful in the concentration of

The ore which is concentrated by leaching is:

In the extraction of $Al$,the chemical used in the Serpek process is:

In the leaching method,bauxite ore is digested with a concentrated solution of $NaOH$ that produces $X$. When $CO_2$ gas is passed through the aqueous solution of $X$,a hydrated compound $Y$ is precipitated. $X$ and $Y$ respectively are

In the extraction of aluminium:
Process $X$: applied for red bauxite to remove iron oxide (chief impurity).
Process $Y$: (Serpeck's process) applied for white bauxite to remove $Z$ (chief impurity).
Then,process $X$ and impurity $Z$ are:

Which of the following ores is best concentrated by the froth-flotation method?