Choose the correct option for the free expansion of an ideal gas under adiabatic conditions from the following:

For $1 \, \text{mol}$ of an ideal gas,isothermal expansion occurs from $1 \, \text{L}$ to $10 \, \text{L}$ in a vacuum at $300 \, \text{K}$. What is the value of $\Delta U$ for this process? $(R = 2 \, \text{cal} \, \text{K}^{-1} \, \text{mol}^{-1})$

$A$ system receives $224 \ J$ of heat and does $156 \ J$ of work. Calculate the change in internal energy. (in $J$)

For water at $100^{\circ} C$ and $1 \, bar$,$\Delta_{vap} H - \Delta_{vap} U = ...... \times 10^{2} \, J \, mol^{-1}$. (Round off to the Nearest Integer) $[Use : R = 8.31 \, J \, mol^{-1} \, K^{-1}]$ [Assume volume of $H_{2}O_{(\ell)}$ is much smaller than volume of $H_{2}O_{(g)}$. Assume $H_{2}O_{(g)}$ treated as an ideal gas]

$C_2H_5OH(l) + 3O_2(g) \rightarrow 2CO_2(g) + 3H_2O(l)$. The enthalpy change $(\Delta H)$ for the above reaction at $27^{\circ}C$ is $-1366.5 \text{ kJ mol}^{-1}$. Calculate the internal energy change $(\Delta U)$ for the same reaction at this temperature.

Which of the following relations is correct for the reaction $S(s) + O_2(g) \rightarrow SO_2(g)$?