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Which of the following statements is correct?

Which of the following is a mineral of copper?

The metal which mainly occurs as oxide ore in nature is

Match the following ores/compounds in Column $I$ with their chemical formulas in Column $II$:
Column $I$ Column $II$
$1$. Chromite $P$. $ZnS$
$2$. Malachite $Q$. $FeO \cdot Cr_2O_3$
$3$. Cryolite $R$. $CuCO_3 \cdot Cu(OH)_2$
$4$. Zinc Blende $S$. $Na_3AlF_6$

Select the correct statement:

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