Compare the two methods shown for the preparation of carboxylic acids.
Method $1$: $RBr$ $\xrightarrow[diethyl \ ether]{Mg} RMgBr$ $\xrightarrow[2. \ H_3O^{+}]{1. \ CO_2} RCO_2H$
Method $2$: $RBr$ $\xrightarrow{NaCN} RCN$ $\xrightarrow[heat]{H_2O, HCl} RCO_2H$
Which one of the following statements correctly describes this conversion for the given substrate ($1$-bromoadamantane)?

  • A
    Both Method $1$ and Method $2$ are appropriate for carrying out this conversion.
  • B
    Neither Method $1$ nor Method $2$ is appropriate for carrying out this conversion.
  • C
    Method $1$ will work well,but Method $2$ is not appropriate.
  • D
    Method $2$ will work well,but Method $1$ is not appropriate.

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$(A)$ $R-C \equiv N \xrightarrow[(i) H^{+}/H_2O]{\text{mild condition}} R-CONH_2$
$(B)$ $R-MgX \xrightarrow[(ii) H_3O^{+}]{\text{(i) } CO_2} R-COOH$
$(C)$ $R-C \equiv N \xrightarrow[(ii) H_3O^{+}]{\text{(i) } SnCl_2/HCl} R-CHO$
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Choose the correct answer from the options given below:

What is $C$ in the following sequence of reaction?
$CH_3OH$ $\xrightarrow{PCl_3} A$ $\xrightarrow{KCN} B$ $\xrightarrow{\text{Hydrolysis}} C$

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