Which of the following complexes shows linkag | vedclass

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(C) Linkage isomerism occurs in coordination compounds containing ambidentate ligands,which can coordinate through two different donor atoms.In the co

Vedclass · Accepted Answer

$[Co(en)_2(NO_2)Cl]Br$

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(C) Linkage isomerism occurs in coordination compounds containing ambidentate ligands,which can coordinate through two different donor atoms.In the complex $[Co(en)_2(NO_2)Cl]Br$,the ligand $NO_2^-$ is an ambidentate ligand.It can coordinate to the central metal atom through the nitrogen atom (as $-NO_2$,nitro) or through the oxygen atom (as $-ONO$,nitrito).Therefore,$[Co(en)_2(NO_2)Cl]Br$ exhibits linkage isomerism.

Which of the following complexes shows linkage isomerism?

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$(i)$ $[Cr(NO_3)_3(NH_3)_3]$
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$(iv)$ $[CoBrCl(en)_2]$

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