Consider an ideal gas with the following distribution of speeds:
Speed $(m/s)$$\%$ of molecules
$200$$10$
$400$$20$
$600$$40$
$800$$20$
$1000$$10$

$(a)$ Calculate $v_{rms}$ and hence $T$. (Given mass of one molecule $m = 3.0 \times 10^{-26} \ kg$, Boltzmann constant $k_B = 1.38 \times 10^{-23} \ J/K$)
$(b)$ If all the molecules with speed $1000 \ m/s$ escape from the system, calculate the new $v_{rms}$ and hence the new $T$.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) The root mean square speed is given by $v_{rms} = \sqrt{\frac{\sum n_i v_i^2}{\sum n_i}}$.
Using the given data:
$v_{rms} = \sqrt{\frac{10(200)^2 + 20(400)^2 + 40(600)^2 + 20(800)^2 + 10(1000)^2}{10+20+40+20+10}}$
$v_{rms} = \sqrt{\frac{10(4 \times 10^4) + 20(16 \times 10^4) + 40(36 \times 10^4) + 20(64 \times 10^4) + 10(100 \times 10^4)}{100}}$
$v_{rms} = \sqrt{\frac{10^4(40 + 320 + 1440 + 1280 + 1000)}{100}} = \sqrt{408000} \approx 638.75 \ m/s$.
Using $v_{rms} = \sqrt{\frac{3k_B T}{m}}$, we get $T = \frac{m v_{rms}^2}{3k_B} = \frac{3.0 \times 10^{-26} \times (638.75)^2}{3 \times 1.38 \times 10^{-23}} \approx 0.098 \ K$.
$(b)$ Removing molecules with $v = 1000 \ m/s$, the new distribution has $90$ molecules total.
$v_{rms}' = \sqrt{\frac{10(200)^2 + 20(400)^2 + 40(600)^2 + 20(800)^2}{90}}$
$v_{rms}' = \sqrt{\frac{10^4(40 + 320 + 1440 + 1280)}{90}} = \sqrt{\frac{3080000}{90}} \approx 585.18 \ m/s$.
$T' = \frac{m (v_{rms}')^2}{3k_B} = \frac{3.0 \times 10^{-26} \times (585.18)^2}{3 \times 1.38 \times 10^{-23}} \approx 0.082 \ K$.

Explore More

Similar Questions

The r.m.s. speed of hydrogen at $S.T.P.$ is $u \text{ m/s}$. If the gas is heated at constant pressure till its volume becomes three times, the final temperature of the gas and the r.m.s. speed are respectively:

Uranium has two isotopes of masses $235$ and $238$ units. If both of them are present in uranium hexafluoride gas, find the percentage ratio of the difference in rms velocities of the two isotopes to the rms velocity of the heavier isotope.

For a gas at a temperature $T$,the root-mean-square velocity ${v_{rms}}$,the most probable speed ${v_{mp}}$,and the average speed ${v_{av}}$ obey the relationship:

Five gas molecules chosen at random are found to have speeds of $500, 600, 700, 800$ and $900 \ m/s$. Which of the following statements is correct?

The r.m.s. speed of gas molecules is given by

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo