Consider the following complexes:
$(a) K_2PtCl_6$
$(b) PtCl_4 \cdot 2NH_3$
$(c) PtCl_4 \cdot 3NH_3$
$(d) PtCl_4 \cdot 5NH_3$
Their electrical conductances in aqueous solutions are:

  • A
    $256, 0, 97, 404$
  • B
    $404, 0, 97, 256$
  • C
    $256, 97, 0, 404$
  • D
    $404, 97, 256, 0$

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The stepwise formation of $[Cu(NH_{3})_{4}]^{2+}$ is given below:
$Cu^{2+} + NH_{3} \rightleftharpoons [Cu(NH_{3})]^{2+} \quad K_{1}$
$[Cu(NH_{3})]^{2+} + NH_{3} \rightleftharpoons [Cu(NH_{3})_{2}]^{2+} \quad K_{2}$
$[Cu(NH_{3})_{2}]^{2+} + NH_{3} \rightleftharpoons [Cu(NH_{3})_{3}]^{2+} \quad K_{3}$
$[Cu(NH_{3})_{3}]^{2+} + NH_{3} \rightleftharpoons [Cu(NH_{3})_{4}]^{2+} \quad K_{4}$
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(Rounded off to the nearest integer)

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