Consider the following statements:
$(1)$ Bridgehead halides are inert towards both $S_{N^1}$ and $S_{N^2}$ reactions (until one of the ring size is an eight-membered ring).
$(2)$ The first step in both $S_{N^1}$ and $E_1$ reactions is the same.
$(3)$ $S_{N^2}$ reactions proceed with total retention of configuration.
$(4)$ $E_2$ eliminations are favored by the use of a solvent of low polarity and a high concentration of a strong base.
Which of the above statements are correct?

  • A
    $1, 2$ and $4$
  • B
    $1$ and $3$
  • C
    $2, 3$ and $4$
  • D
    $1, 2, 3$ and $4$

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Which of the following is $NOT$ obtained when a mixture of chloroethane and $1-$chloropropane is treated with sodium metal in dry ether?

What happens when
$(i)$ $n$-butyl chloride is treated with alcoholic $KOH$.
$(ii)$ bromobenzene is treated with $Mg$ in the presence of dry ether.
$(iii)$ chlorobenzene is subjected to hydrolysis.
$(iv)$ ethyl chloride is treated with aqueous $KOH$.
$(v)$ methyl bromide is treated with sodium in the presence of dry ether.
$(vi)$ methyl chloride is treated with $KCN$?

Chlorination of substance $A$ gives substance $B$. Substance $B$ reacts with alcoholic $KOH$ to give substance $C$,which decolorizes Baeyer's reagent. Ozonolysis of substance $C$ gives $HCHO$. What is substance $A$?

Match the reactants in Column-$I$ with their products in Column-$II$.
Column-$I$ (Reactants)Column-$II$ (Products)
$A$. $H_2C=CH_2 + Br_2 \xrightarrow{CCl_4}$$i$. $CH_3CH_2CH_2Br$
$B$. $CH_3CH=CH_2 + HI \rightarrow$$ii$. $BrCH_2-CH_2Br$
$C$. $C_6H_5N_2^+X^- + KI \rightarrow$$iii$. $CH_3CHICH_3$
$D$. $CH_3CH=CH_2 + HBr \xrightarrow{peroxide}$$iv$. $C_6H_5I$

Identify the major product formed from the following reaction sequence:

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