Consider the following statements about Langmuir isotherm.
$I.$ The free gas and adsorbed gas are in dynamic equilibrium.
$II.$ All adsorption sites are equivalent.
$III.$ The initially adsorbed layer can act as a substrate for further adsorption.
$IV.$ The ability of a molecule to get adsorbed at a given site is independent of the occupation of neighboring sites.
The correct statements are
$I.$ The free gas and adsorbed gas are in dynamic equilibrium.
$II.$ All adsorption sites are equivalent.
$III.$ The initially adsorbed layer can act as a substrate for further adsorption.
$IV.$ The ability of a molecule to get adsorbed at a given site is independent of the occupation of neighboring sites.
The correct statements are
- A$I, II, III$ and $IV$
- B$I, II$ and $IV$
- C$I, III,$ and $IV$
- D$I, II,$ and $III$
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Three rods of equal lengths are joined to form an equilateral triangle $ABC$. $D$ is the mid-point of $AB$. The coefficient of linear expansion is $\alpha_1$ for the material of rod $AB$ and $\alpha_2$ for the material of rods $AC$ and $BC$. If the distance $DC$ remains constant for small changes in temperature,then
The major products obtained from the reactions in List$-II$ are the reactants for the named reactions mentioned in List$-I.$ Match each entry in List$-I$ with the appropriate entry in List$-II$ and choose the correct options.
List$-I$
List$-II$
$(P)$ Stephen reaction
$(1)$ Toluene $\xrightarrow{\substack{\text { (i) } CrO _2 Cl _2 / CS _2 \\ \text { (ii) } H _3 O +}}$
$(Q)$ Sandmeyer reaction
$(2)$ Benzoic acid $\xrightarrow{\substack{\text { (i) } PCl _5 \\ \text { (iii) } NH _3 \\ \text { (iii) } P _4 O _{10}, \Delta}}$
$(R)$ Hoffmann bromamide degradation reaction
$(3)$ Nitrobenzene $\xrightarrow{\begin{array}{l}\text { (i) } Fe , HCl \\ \text { (ii) } HCl , NaNO _2 \\ \text { (273-278 K), } H _2 O \end{array}}$
$(S)$ Cannizzaro reaction
$(4)$ Toluene $\xrightarrow{\begin{array}{l}\text { (i) } Cl _2 / hv , H _2 O \\ \text { (ii) } \text {Tollen 's reagent } \\ \text { (iii) } SO _2 Cl _2 \\ \text { (iv) } NH _3\end{array}}$
$(5)$ Aniline $\xrightarrow{\substack{\text { (i) }\left( CH _3 CO \right)_2 O , \text { Pyridine } \\ \text { (ii) } HN O _3 H _{2} SO _4, 288 K \\ \text { (iii) } aq . NaOH }}$
| List$-I$ | List$-II$ |
| $(P)$ Stephen reaction | $(1)$ Toluene $\xrightarrow{\substack{\text { (i) } CrO _2 Cl _2 / CS _2 \\ \text { (ii) } H _3 O +}}$ |
| $(Q)$ Sandmeyer reaction | $(2)$ Benzoic acid $\xrightarrow{\substack{\text { (i) } PCl _5 \\ \text { (iii) } NH _3 \\ \text { (iii) } P _4 O _{10}, \Delta}}$ |
| $(R)$ Hoffmann bromamide degradation reaction | $(3)$ Nitrobenzene $\xrightarrow{\begin{array}{l}\text { (i) } Fe , HCl \\ \text { (ii) } HCl , NaNO _2 \\ \text { (273-278 K), } H _2 O \end{array}}$ |
| $(S)$ Cannizzaro reaction | $(4)$ Toluene $\xrightarrow{\begin{array}{l}\text { (i) } Cl _2 / hv , H _2 O \\ \text { (ii) } \text {Tollen 's reagent } \\ \text { (iii) } SO _2 Cl _2 \\ \text { (iv) } NH _3\end{array}}$ |
| $(5)$ Aniline $\xrightarrow{\substack{\text { (i) }\left( CH _3 CO \right)_2 O , \text { Pyridine } \\ \text { (ii) } HN O _3 H _{2} SO _4, 288 K \\ \text { (iii) } aq . NaOH }}$ |
In the equation $\log\ S = \log\ C + Z\ \log\ A$,what does $C$ represent?
Which one of the following is more readily hydrolysed by $S_{N}1$ mechanism?
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