Consider the given energy profile diagram for a reaction and choose the correct option:

  • A
    Activation energy of backward reaction is $E_1$ and product is more stable than reactant.
  • B
    Activation energy of forward reaction is $E_1+E_2$ and product is more stable than reactant.
  • C
    Activation energy of forward reaction is $E_1+E_2$ and product is less stable than reactant.
  • D
    Activation energy of both forward and backward reaction is $E_1+E_2$ and reactant is more stable than product.

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The activation energy of a reaction at a given temperature is found to be $2.303 \ RT \ J \ mol^{-1}$. The ratio of rate constant to the Arrhenius factor is

For the gaseous reactions,calculate the approximate value of temperature at which $k_1 = k_2$. $[\ln\, 10 = 2.3]$.
$A \to B$ $k_1 = 10^{15} e^{-25000 / 8.314\, T}$
$C \to D$ $k_2 = 10^{14} e^{-15000 / 8.314\, T}$

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