Consider the reaction $K_2[Ni(CN)_4] + 4K + 4NH_3 \to A$ (complex $A$).
Complex $A$ gives five ions in aqueous solution. Choose the $CORRECT$ statements.

  • A
    Complex is $sp^3$ hybridised & diamagnetic
  • B
    Complex is $sp^3$ hybridised and paramagnetic
  • C
    Complex is $dsp^2$ hybridised and diamagnetic
  • D
    In complex $CN^-$ ligands are replaced by $NH_3$ ligands

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Match the coordination number and type of hybridisation with distribution of hybrid orbitals in space based on Valence bond theory.
Coordination number and type of hybridisation Distribution of hybrid orbitals in space
$(a)$. $4, sp^3$ $(i)$. trigonal bipyramidal
$(b)$. $3, sp^2$ $(ii)$. octahedral
$(c)$. $5, sp^3 d$ $(iii)$. tetrahedral
$(d)$. $6, sp^3 d^2$ $(iv)$. trigonal planar

Select the correct option $:$

Point out the correct statements amongst the following.

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Which of the following is an outer orbital complex?

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The statements that are incorrect about the nickel$(II)$ complex of dimethylglyoxime are:
$A$. It is red in colour
$B$. It has a high solubility in water at $pH = 9$
$C$. The $Ni$ ion has two unpaired $d$-electrons
$D$. The $N - Ni - N$ bond angle is almost close to $90^{\circ}$
$E$. The complex contains four five-membered metallacycles (metal containing rings)
Choose the correct answer from the options given below:

The complex ion $[Cu(NH_3)_4]^{2+}$ is:

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