The correct order of Lewis acidity for BX_3 i | vedclass

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(A) The Lewis acidity of boron trihalides $(BX_3)$ depends on the extent of $p\pi-p\pi$ back-bonding between the halogen atom and the boron atom. In $

Vedclass · Accepted Answer

$BF_3 < BCl_3 < BBr_3 < BI_3$

Vedclass · Answer

(A) The Lewis acidity of boron trihalides $(BX_3)$ depends on the extent of $p\pi-p\pi$ back-bonding between the halogen atom and the boron atom. In $BF_3$,the fluorine atom has a small size and its $2p$ orbitals effectively overlap with the empty $2p$ orbital of boron,leading to strong back-bonding. As the size of the halogen increases from $F$ to $I$,the effectiveness of $p\pi-p\pi$ back-bonding decreases $(F > Cl > Br > I)$. Since back-bonding reduces the electron deficiency of the boron atom,the Lewis acidity increases as the back-bonding decreases. Therefore,the correct order of Lewis acidity is $BF_3 < BCl_3 < BBr_3 < BI_3$.

The correct order of Lewis acidity for $BX_3$ is:

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