The correct relationship between heat of fusion $(\Delta H_{fus})$,heat of vaporization $(\Delta H_{vap})$,and heat of sublimation $(\Delta H_{sub})$ is:

The enthalpy of formation of ammonia is $-46.0 \ kJ \ mol^{-1}$. The enthalpy change for the reaction $2NH_{3(g)} \rightarrow N_{2(g)} + 3H_{2(g)}$ is ............... $kJ \ mol^{-1}$.

Calculate the standard enthalpy of formation of $CH_{3}OH_{(l)}$ from the following data:
$CH_{3}OH_{(l)} + \frac{3}{2} O_{2_{(g)}} \rightarrow CO_{2_{(g)}} + 2 H_{2}O_{(l)}$; $\Delta_{r} H^{\ominus} = -726 \ kJ \ mol^{-1}$
$C_{(graphite)} + O_{2_{(g)}} \rightarrow CO_{2_{(g)}}$; $\Delta_{c} H^{\ominus} = -393 \ kJ \ mol^{-1}$
$H_{2_{(g)}} + \frac{1}{2} O_{2_{(g)}} \rightarrow H_{2}O_{(l)}$; $\Delta_{f} H^{\ominus} = -286 \ kJ \ mol^{-1}$

Consider the following data:
$\Delta_{f}H^{\Theta}(CH_{4}, g) = -X \ kJ \ mol^{-1}$
Enthalpy of sublimation of graphite = $Y \ kJ \ mol^{-1}$
Dissociation enthalpy of $H_{2} = Z \ kJ \ mol^{-1}$
The bond enthalpy of $C-H$ bond is given by:

What is meant by the term average bond enthalpy? Why is there a difference in the bond enthalpy of the $O-H$ bond in ethanol $(C_{2}H_{5}OH)$ and water $(H_{2}O)$?

Identify the factor from the following on which the heat of reaction does not depend.