Do you expect different products in solution when aluminium $(III)$ chloride and potassium chloride are treated separately with $(i)$ normal water,$(ii)$ acidified water,and $(iii)$ alkaline water? Write equations wherever necessary.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) Potassium chloride $(KCl)$ is the salt of a strong acid $(HCl)$ and a strong base $(KOH)$. Hence,it is neutral in nature and does not undergo hydrolysis in normal water. It dissociates into ions as follows:
$KCl_{(s)} \xrightarrow{H_2O} K_{(aq)}^{+} + Cl_{(aq)}^{-}$
In acidified and alkaline water,the ions do not react and remain as such.
Aluminium $(III)$ chloride $(AlCl_3)$ is the salt of a strong acid $(HCl)$ and a weak base $[Al(OH)_3]$. Hence,it undergoes hydrolysis in normal water:
$AlCl_{3(s)} + 3H_2O_{(l)} \to Al(OH)_{3(s)} + 3H^+_{(aq)} + 3Cl^-_{(aq)}$
In acidified water,$H^+$ ions suppress the hydrolysis of $Al^{3+}$,so $AlCl_3$ exists as $Al^{3+}_{(aq)}$ and $Cl^-_{(aq)}$ ions:
$AlCl_{3(s)} \xrightarrow{H^+_{(aq)}} Al^{3+}_{(aq)} + 3Cl^-_{(aq)}$
In alkaline water,the $Al(OH)_3$ formed reacts with $OH^-$ ions to form a soluble complex:
$Al(OH)_{3(s)} + OH^-_{(aq)} \to [Al(OH)_4]^-_{(aq)}$

Explore More

Similar Questions

On dilution,the $pH$ of $CH_3COONH_4$ solution:

The aqueous solution of sodium acetate is:

The aqueous solution of sodium cyanide $(NaCN)$ is:

If $0.1 \, M \, CH_3COONa$ undergoes $1 \%$ hydrolysis,then the values of $K_h$,$K_a$ of the acid,and the concentration of $CH_3COOH$ are respectively:

Ionization constants for $CH_3COOH$ and $HCN$ are respectively $1.8 \times 10^{-5}$ and $7.2 \times 10^{-10}$. The degree of hydrolysis of $0.1 \ M \ KCN$ $(h_1)$ and $0.1 \ M \ CH_3COOK$ $(h_2)$ follows the order :

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo