During the kinetic study of the reaction,$2A + B \rightarrow C + D,$ the following results were obtained:
$Run$ $[A] / mol \ L^{-1}$ $[B] / mol \ L^{-1}$ Initial rate of formation of $D / mol \ L^{-1} \ min^{-1}$
$I.$ $0.1$ $0.1$ $6.0 \times 10^{-3}$
$II.$ $0.3$ $0.2$ $7.2 \times 10^{-2}$
$III.$ $0.3$ $0.4$ $2.88 \times 10^{-1}$
$IV.$ $0.4$ $0.1$ $2.40 \times 10^{-2}$

Based on the above data,which one of the following is correct?

  • A
    Rate $= k[A]^2[B]$
  • B
    Rate $= k[A][B]$
  • C
    Rate $= k[A]^2[B]^2$
  • D
    Rate $= k[A][B]^2$

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Identify the reaction intermediate of the following reaction sequence:
$(i)$ $2 SO_{2(g)} + 2 NO_{2(g)} \rightarrow 2 SO_{3(g)} + 2 NO_{(g)}$
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--------------------------------------------------
Overall: $2 SO_{2(g)} + O_{2(g)} \rightarrow 2 SO_{3(g)}$

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