Ethanol on reaction with acetic anhydride gives

The product $(A)$ of the reaction is:

Select the $CORRECT$ increasing order of boiling points of alcohols,amines,and carboxylic acids of comparable molar mass from the following.

The reagent$(s)$ required for the following conversion are:

In Column - $I$ the structure of the compound is given,in Column - $II$ the boiling point,and in Column - $III$ the functional group is given. Find the correct match for Column - $I$ from Column - $II$ and Column - $III$.

Column - $I$ (Formula)	Column - $II$ (Boiling Point)	Column - $III$ (Group)
$(A)$ $CH_3COOH$	$(i)$ $309 \ K$	$(m)$ Alkane
$(B)$ $CH_3CH_2CH_2OH$	$(ii)$ $322 \ K$	$(n)$ Ketone
$(C)$ $CH_3COCH_3$	$(iii)$ $329 \ K$	$(o)$ Aldehyde
$(D)$ $CH_3CH_2CHO$	$(iv)$ $391 \ K$	$(p)$ Carboxylic acid
$(E)$ $CH_3CH_2CH_2CH_2CH_3$	$(v)$ $370 \ K$	$(q)$ Alcohol

Draw the structures of the following compounds:
$(i)$ $3-$Methylbutanal
$(ii)$ $p-$Nitropropiophenone
$(iii)$ $p-$Methylbenzaldehyde
$(iv)$ $4-$Methylpent$-3-$en$-2-$one
$(v)$ $4-$Chloropentan$-2-$one
$(vi)$ $3-$Bromo$-4-$phenylpentanoic acid
$(vii)$ $p, p^{\prime}-$Dihydroxybenzophenone
$(viii)$ Hex$-2-$en$-4-$ynoic acid