Explain the extraction of iron from its oxide ores.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) The extraction of iron from its oxide ores $(Fe_{2}O_{3}, Fe_{3}O_{4})$ involves the following steps:
$1$. Concentration and Calcination: After concentration,the ore is subjected to calcination/roasting to remove moisture,decompose carbonates,and oxidize any sulphide impurities.
$2$. Blast Furnace Process: The concentrated ore is mixed with limestone $(CaCO_{3})$ and coke $(C)$ and fed into a blast furnace from the top.
$3$. Chemical Reactions in Blast Furnace:
- At the top (lower temperature,$500-800 \ K$): The iron oxides are reduced by $CO$ gas.
$3Fe_{2}O_{3} + CO \rightarrow 2Fe_{3}O_{4} + CO_{2}$
$Fe_{3}O_{4} + CO \rightarrow 3FeO + CO_{2}$
- At the middle (higher temperature,$900-1500 \ K$): $FeO$ is reduced to metallic iron.
$FeO + CO \rightarrow Fe + CO_{2}$
$C + CO_{2} \rightarrow 2CO$
- Limestone decomposes to $CaO$,which reacts with silica $(SiO_{2})$ impurity to form slag $(CaSiO_{3})$.
$CaCO_{3} \rightarrow CaO + CO_{2}$
$CaO + SiO_{2} \rightarrow CaSiO_{3}$
- At the bottom (very high temperature,up to $2200 \ K$): Coke burns to provide heat and $CO$ for reduction.
$C + O_{2} \rightarrow CO_{2}$
$FeO + C \rightarrow Fe + CO$

Explore More

Similar Questions

State the important features of Ellingham diagram. Also state its limitations.

In the extraction of iron from haematite,the impurity $(x)$ of the ore is removed in the form of '$y$'. What are $x$ and $y$ respectively?

What is blister copper?

Limestone is used as a flux in the extraction of

Which of the following oxides is not reduced by carbon reduction for its commercial extraction?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo