Explain the following:
$(1)$ $BF_3$ does not hydrolyze.
$(2)$ Why does the element silicon not form a graphite-like structure,whereas carbon does?

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) $(1)$ $BF_3$ undergoes partial hydrolysis. The $HF$ produced reacts with $H_3BO_3$ to form fluoroboric acid,preventing complete hydrolysis:
$4BF_3 + 3H_2O \rightarrow H_3BO_3 + 3H^+ + 3[BF_4]^-$
$(2)$ In graphite,carbon atoms are $sp^2$ hybridized and form $p\pi-p\pi$ double bonds due to their small size and high electronegativity. Silicon,due to its larger atomic size and lower electronegativity,cannot form stable $p\pi-p\pi$ multiple bonds,and therefore cannot form a graphite-like structure.

Explore More

Similar Questions

Which one of the following elements does not form triiodide on reacting with iodine?

An aqueous solution of borax is

Aluminum dissolves in mineral acids and aqueous alkalis and thus shows amphoteric character. $A$ piece of aluminum foil is treated with dilute hydrochloric acid or dilute sodium hydroxide solution in a test tube and on bringing a burning match stick near the mouth of the test tube,a pop sound indicates the evolution of hydrogen gas. The same activity when performed with concentrated nitric acid,the reaction does not proceed. Explain the reason.

Statement-$1$: Orthoboric acid acts as a weak monobasic acid in water.
Statement-$2$: Orthoboric acid acts as a proton donor in water.

Which of the following on hydrolysis produces diborane $(B_2H_6)$?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo