Fill in the blanks:
$1.$ The rate of reaction depends on the ........... step.
$2.$ In a bimolecular reaction,the reaction takes place with ........... species and ........... .
$3.$ The order of reaction is determined by ...........

Which of the following statements is false?

$[A]_0 / \text{mol } L^{-1}$	$t_{1/2} / \text{min}$
$0.100$	$200$
$0.025$	$100$

For a given reaction $R \rightarrow P$,$t_{1/2}$ is related to $[A]_0$ as given in the table:
Given: $\log 2 = 0.30$
Which of the following is true?
$A.$ The order of the reaction is $1/2$.
$B.$ If $[A]_0$ is $1 \text{ M}$,then $t_{1/2}$ is $200 \sqrt{10} \text{ min}$.
$C.$ The order of the reaction changes to $1$ if the concentration of reactant changes from $0.100 \text{ M}$ to $0.500 \text{ M}$.
$D.$ $t_{1/2}$ is $800 \text{ min}$ for $[A]_0 = 1.6 \text{ M}$.
Choose the correct answer from the options given below:

The following data are for the decomposition of ammonium nitrate in aqueous solution. The order of the reaction is:

$N_2$ volume in $cc$ $(V_t)$	$6.25$	$9.50$	$11.42$	$13.65$	$35.05$ $(V_{\infty})$
Time $(t)$ in minutes	$10$	$15$	$20$	$25$	$\infty$

Assertion : In rate law,unlike in the expression for equilibrium constants,the exponents for concentrations do not necessarily match the stoichiometric coefficients.
Reason : It is the mechanism and not the balanced chemical equation for the overall change that governs the reaction rate.

For a chemical reaction $Y + 2Z \to$ Product,the rate-controlling step is $Y + \frac{1}{2}Z \to Q$. If the concentration of $Z$ is doubled,the rate of reaction will: