Medium
Find the rate law for the reaction,$CHCl_{3(g)} + Cl_{2(g)} \rightarrow CCl_{4(g)} + HCl_{(g)}$ if the order of reaction with respect to $CHCl_{3(g)}$ is $1$ and with respect to $Cl_{2(g)}$ is $1/2$.
- ARate $= k[CHCl_3][Cl_2]^{1/2}$
- BRate $= k[CHCl_3]^2[Cl_2]^{1/2}$
- CRate $= k[CHCl_3]^{3/2}[Cl_2]$
- DRate $= k[CHCl_3]^{1/2}[Cl_2]$
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Similar Questions
For the reaction $2A + 2B \rightarrow 2C + D$,if $r = k[A]^2[B]^0$,then the rate of reaction is:
$2 \ NO + 2 \ H_2 \rightarrow N_2 + 2 \ H_2O$
The above reaction has been studied at $800^{\circ} C$. The related data are given in the table below.
Reaction serial number Initial pressure of $H_2$ / $kPa$ Initial Pressure of $NO$ / $kPa$ Initial rate $(-\frac{dp}{dt}) / (kPa \ s^{-1})$ $1$ $65.6$ $40.0$ $0.135$ $2$ $65.6$ $20.1$ $0.033$ $3$ $38.6$ $65.6$ $0.214$ $4$ $19.2$ $65.6$ $0.106$
The order of the reaction with respect to $NO$ is $...........$
The above reaction has been studied at $800^{\circ} C$. The related data are given in the table below.
| Reaction serial number | Initial pressure of $H_2$ / $kPa$ | Initial Pressure of $NO$ / $kPa$ | Initial rate $(-\frac{dp}{dt}) / (kPa \ s^{-1})$ |
| $1$ | $65.6$ | $40.0$ | $0.135$ |
| $2$ | $65.6$ | $20.1$ | $0.033$ |
| $3$ | $38.6$ | $65.6$ | $0.214$ |
| $4$ | $19.2$ | $65.6$ | $0.106$ |
The order of the reaction with respect to $NO$ is $...........$
For the reaction $A + B \xrightarrow{K} C$,identify the incorrect order of reaction indicated against the rate expression.
Easy
View SolutionIn the given reaction sequence,if $K_3 > K_2 > K_1$,then the rate-determining step is:
Easy
View SolutionFor the decomposition of a compound $AB$ at $600 \ K$,the following data were obtained:
$[AB] \ (mol \ dm^{-3})$ Rate of decomposition of $AB \ (mol \ dm^{-3} \ s^{-1})$ $0.20$ $2.75 \times 10^{-8}$ $0.40$ $11.0 \times 10^{-8}$ $0.60$ $24.75 \times 10^{-8}$
The order for the decomposition of $AB$ is:
| $[AB] \ (mol \ dm^{-3})$ | Rate of decomposition of $AB \ (mol \ dm^{-3} \ s^{-1})$ |
| $0.20$ | $2.75 \times 10^{-8}$ |
| $0.40$ | $11.0 \times 10^{-8}$ |
| $0.60$ | $24.75 \times 10^{-8}$ |
The order for the decomposition of $AB$ is:
DifficultKCET 2009
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