Find the value $\Delta H_f^o[NH_{3(g)}]$ if $\Delta H_r$ for the reaction $N_{2(g)} + 3H_{2(g)} \to 2NH_{3(g)}$ is $-\,183.6 \ kJ/mol$ of $N_{2(g)}$.

For which of the following reactions will the value of $\Delta H$ be positive?

Based on the following thermochemical equations,find the value of $x$ in $kJ$.
$(i) \ H_2O_{(g)} + C_{(s)} \to CO_{(g)} + H_{2(g)} ; \Delta H = 131 \ kJ$
$(ii) \ CO_{(g)} + \frac{1}{2} O_{2(g)} \to CO_{2(g)} ; \Delta H = -282 \ kJ$
$(iii) \ H_{2(g)} + \frac{1}{2} O_{2(g)} \to H_2O_{(g)} ; \Delta H = -242 \ kJ$
$(iv) \ C_{(s)} + O_{2(g)} \to CO_{2(g)} ; \Delta H = -x \ kJ$

The bond energies of $H-H$ and $Cl-Cl$ are $430 \, kJ/mol$ and $240 \, kJ/mol$ respectively. If $\Delta_f H$ for $HCl$ is $-90 \, kJ/mol$,then the bond enthalpy of $HCl$ will be ...... $kJ/mol$.

The heat of formation of $SiO_2$ and $MgO$ is respectively $-48.4 \ kJ$ and $-34.7 \ kJ$. The heat of the reaction $2Mg + SiO_2 \to 2MgO + Si$ is $...... \ kJ$.

The atomisation enthalpy of $CH_4$ is $1660 \ kJ \ mol^{-1}$. The $C-H$ bond enthalpy of each successive step in $CH_4$ $\rightarrow CH_3$ $\rightarrow CH_2$ $\rightarrow CH$ are $+15, +30$ and $+45 \ kJ \ mol^{-1}$ higher than the mean bond enthalpy of $C-H$ bonds,respectively. The bond enthalpy of the last $C-H$ unit is