Find True $(T)$ and False $(F)$ statements in the following:
$1.$ Effective collision depends on rate.
$2.$ When the reactant converts into product,the bonds in the reactant break and new bonds form.
$3.$ The breaking of old bonds and the formation of new bonds take place simultaneously.

  • A
    $1-T, 2-T, 3-T$
  • B
    $1-F, 2-T, 3-T$
  • C
    $1-F, 2-F, 3-T$
  • D
    $1-T, 2-F, 3-F$

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Consider the following statements related to the temperature dependence of rate constants. Identify the correct statements:
$A.$ The Arrhenius equation holds true only for an elementary homogeneous reaction.
$B.$ The unit of $A$ is the same as that of $k$ in the Arrhenius equation.
$C.$ At a given temperature,a low activation energy means a fast reaction.
$D.$ $A$ and $E_a$ as used in the Arrhenius equation depend on temperature.
$E.$ When $E_a > RT$,$A$ and $E_a$ become interdependent.
Choose the correct answer from the options given below:

$A$ reaction takes place in three steps with individual rate constant and activation energy,
Step Rate constant and Activation energy
$Step \ 1$ $k_1, E_{a_1} = 180 \ kJ \ mol^{-1}$
$Step \ 2$ $k_2, E_{a_2} = 80 \ kJ \ mol^{-1}$
$Step \ 3$ $k_3, E_{a_3} = 50 \ kJ \ mol^{-1}$

Overall rate constant,$k = (k_1 k_2 / k_3)^{2/3}$. The overall activation energy of the reaction will be ........ $kJ \ mol^{-1}$.

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The rate of a chemical reaction doubles for every $10^\circ \text{C}$ rise in temperature. If the temperature is increased by $50^\circ \text{C}$,the rate of reaction will increase by a factor of ........

The rate constants $k_1$ and $k_2$ for two different reactions are $10^{16} \times e^{-2000/T}$ and $10^{15} \times e^{-1000/T}$ respectively. The temperature at which $k_1 = k_2$ is

Half life of a first order reaction is $900 \ \text{min}$ at $400 \ K$. Find its half life at $300 \ K$. Given: $\frac{E_a}{2.303 \ R} = 1.3056 \times 10^3 \ K$. (in $\text{min}$)

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