For a diatomic ideal gas in a closed system,which of the following plots does not correctly describe the relation between various thermodynamic quantities?

Identify the correct statements from the following.
$I$. At $0 \ K$,the entropy of pure crystalline materials approaches zero.
$II$. Entropy for the process,$H_2O_{(l)} \longrightarrow H_2O_{(g)}$ decreases.
$III$. Gibbs' energy is a state function.

$A$ $10 \ g$ piece of iron $(C = 0.45 \ J/g \ ^oC)$ at $100 \ ^oC$ is dropped into $25 \ g$ of water $(C = 4.2 \ J/g \ ^oC)$ at $27 \ ^oC$. Find the temperature of the iron and water system at thermal equilibrium in $^oC$.

If the standard enthalpy of sublimation $(\Delta_{sub} H^{\circ})$ of solid $CO_2$,naphthalene,$Li$ and $Na$ are $25.2, 73.0, 162, 108 \ kJ \ mol^{-1}$ respectively,the order of ease of sublimation of these substances is:

Consider the following statements:
Statement-$I$: Both internal energy $(U)$ and work $(w)$ are state functions.
Statement-$II$: During the free expansion of an ideal gas into vacuum,the work done is zero.
The correct answer is:

The ratio of heats liberated at $298 \ K$ from the combustion of one $kg$ of coke and by burning water gas obtained from $1 \ kg$ of coke is. (Assume coke to be $100 \%$ carbon.) (Given enthalpies of combustion of $CO_{2}, CO$ and $H_{2}$ as $393.5 \ kJ/mol, 283.5 \ kJ/mol, 285.5 \ kJ/mol$ respectively all at $298 \ K$.) (in $: 1$)