For a first order reaction $A \rightarrow P$,the temperature $(T)$ dependent rate constant $(k)$ was found to follow the equation $\log k = -(2000) \frac{1}{T} + 6.0$. The pre-exponential factor $A$ and the activation energy $E_{a}$,respectively,are

  • A
    $1.0 \times 10^6 \ s^{-1}$ and $9.2 \ kJ \ mol^{-1}$
  • B
    $6.0 \ s^{-1}$ and $16.6 \ kJ \ mol^{-1}$
  • C
    $1.0 \times 10^6 \ s^{-1}$ and $16.6 \ kJ \ mol^{-1}$
  • D
    $1.0 \times 10^6 \ s^{-1}$ and $38.3 \ kJ \ mol^{-1}$

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$A$ plot of $ \frac{1}{T} $ vs. $ \ln k $ for a reaction gives the slope $ -1 \times 10^{4} \ K $. The energy of activation for the reaction is (Given $ R = 8.314 \ J \ K^{-1} \ mol^{-1} $)

What happens to the most probable kinetic energy and the energy of activation with an increase in temperature?

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Consider the following transformation involving first order elementary reactions in each step at constant temperature as shown below.
$A + B \underset{\text{Step } 3}{\overset{\text{Step } 1}{\rightleftharpoons}} C \xrightarrow{\text{Step } 2} P$
Some details of the above reaction are listed below.
Step Rate constant $(s^{-1})$ Activation energy $(kJ \ mol^{-1})$
$1$ $k_1$ $300$
$2$ $k_2$ $200$
$3$ $k_3$ $Ea_3$

If the overall rate constant of the above transformation $(k)$ is given as $k = \frac{k_1 k_2}{k_3}$ and the overall activation energy $(E_a)$ is $400 \ kJ \ mol^{-1}$,then the value of $Ea_3$ is $\qquad$ $kJ \ mol^{-1}$ (nearest integer).

The rate of a reaction doubles,when the temperature is changed from $300 \ K$ to $310 \ K$. Activation energy of the reaction is....... $(R=8.314 \ J \ K^{-1} \ mol^{-1}, \log 2=0.301)$

For a reaction,the activation energy $E_{a} = 0$ and the rate constant at $200 \ K$ is $1.6 \times 10^{6} \ s^{-1}$. The rate constant at $400 \ K$ will be (given $R = 8.314 \ J \ K^{-1} \ mol^{-1}$):

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