For a reaction,given below is the graph of $\ln k$ vs $\frac{1}{T}$. The activation energy for the reaction is equal to $...... \ cal \ mol^{-1}$. (Nearest integer). (Given : $R = 2 \ cal \ K^{-1} \ mol^{-1}$)

  • A
    $8$
  • B
    $40$
  • C
    $4$
  • D
    $20$

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For a reversible reaction $A \rightleftharpoons B$,the $\Delta H_{\text{forward}} = 20 \ kJ \ mol^{-1}$. The activation energy of the uncatalysed forward reaction is $300 \ kJ \ mol^{-1}$. When the reaction is catalysed keeping the reactant concentration same,the rate of the catalysed forward reaction at $27^{\circ}C$ is found to be same as that of the uncatalysed reaction at $327^{\circ}C$. The activation energy of the catalysed backward reaction is $.... \ kJ \ mol^{-1}$.

Which of the following statements is correct regarding the Arrhenius equation and reaction kinetics?

The rate constant for the reaction,$COCl_{2(g)} \longrightarrow CO_{(g)} + Cl_{2(g)}$ is given by $\ln[k / (min^{-1})] = -11067 / T(K) + 31.33$. The temperature at which the rate of this reaction will be doubled from that at $25^{\circ} C$ is $..... \, ^{\circ} C$.

Which of the following is true for a reaction as per collision theory?

The decomposition of $A$ into product has a value of $k$ as $4.5 \times 10^{3} \, s^{-1}$ at $10^{\circ} C$ and an energy of activation of $60 \, kJ \, mol^{-1}$. At what temperature would $k$ be $1.5 \times 10^{4} \, s^{-1}$?

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