For a reaction,the graph of $\ln k$ (on y-axis) and $1 / T$ (on x-axis) is a straight line with a slope $-2 \times 10^4 \ K$. The activation energy of the reaction (in $kJ \ mol^{-1}$) is $(R = 8.3 \ J \ K^{-1} \ mol^{-1})$

Which of the following plots gives the value of activation energy?

Assertion : According to transition state theory for the formation of an activated complex,one of the vibrational degrees of freedom is converted into a translational degree of freedom.
Reason : Energy of the activated complex is higher than the energy of reactant molecules.

The rate constants $k_1$ and $k_2$ for two different reactions are $10^{16} \cdot e^{-2000/T}$ and $10^{15} \cdot e^{-1000/T},$ respectively. The temperature at which $k_1 = k_2$ is

For a chemical reaction at $27^{\circ} C$, the activation energy is $600 R$. The ratio of the rate constants at $327^{\circ} C$ to that of at $27^{\circ} C$ will be

The activation energy of a certain reaction is $87 \ kJ \ mol^{-1}$. When the temperature is decreased from $37^{\circ} C$ to $15^{\circ} C$,what is the ratio of the rate constant at $37^{\circ} C$ to that at $15^{\circ} C$ for this reaction (in $/ 1$)?