For a salt $XY$, which is a strong electrolyte, the plot of $\Lambda_m$ versus $\sqrt{C}$ has a slope of $-90.0 \ S \ cm^2 \ mol^{3/2} \ L^{1/2}$ at $298 \ K$. At $0.01 \ M$ concentration of $XY$, the value of $\Lambda_m$ is $145.5 \ S \ cm^2 \ mol^{-1}$. The limiting molar conductivity of $Y^-$ ion ($\lambda^\circ_{Y^-}$, in $S \ cm^2 \ mol^{-1}$) at $298 \ K$ will be (Given $\lambda^\circ_{X^+} = 74.0 \ S \ cm^2 \ mol^{-1}$) (in $.0$)

  • A
    $80$
  • B
    $100$
  • C
    $90$
  • D
    $76$

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Molar conductivity of a weak acid $HQ$ of concentration $0.18 \ M$ was found to be $1/30$ of the molar conductivity of another weak acid $HZ$ with concentration of $0.02 \ M$. If $\lambda_{Q^{-}}^0 = \lambda_{Z^{-}}^0$, then the difference of the $pK_a$ values of the two weak acids $(pK_a(HQ) - pK_a(HZ))$ is . . . . . . (Nearest integer).
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