For an elementary chemical reaction,$A_2 \underset{k_{-1}}{\overset{k_1}{\longleftrightarrow}} 2A$,the expression for $\frac{d[A]}{dt}$ is

  • A
    $k_1[A_2] - k_{-1}[A]^2$
  • B
    $2k_1[A_2] - k_{-1}[A]^2$
  • C
    $k_1[A_2] + k_{-1}[A]^2$
  • D
    $2k_1[A_2] - 2k_{-1}[A]^2$

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For the reaction $N_2O_5 \rightarrow 2NO_2 + \frac{1}{2} O_2$,given that:
$-\frac{d[N_2O_5]}{dt} = K_1[N_2O_5]$,
$\frac{d[NO_2]}{dt} = K_2[N_2O_5]$,
$\frac{d[O_2]}{dt} = K_3[N_2O_5]$
What is the relationship between $K_1$,$K_2$,and $K_3$?

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