For standardizing $NaOH$ solution,which of the following is used as a primary standard?

  • A
    Sodium tetraborate
  • B
    Ferrous ammonium sulfate
  • C
    Oxalic acid
  • D
    dil. $HCl$

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In a conductometric titration,a small volume of titrant of higher concentration is added stepwise to a larger volume of titrate of much lower concentration,and the conductance is measured after each addition.
The limiting ionic conductivity ( $\Lambda ^0$ ) values (in $mS \ m ^2 \ mol ^{-1}$ ) for different ions in aqueous solutions are given below:
Ions$Ag ^{+}$$K ^{+}$$Na ^{+}$$H ^{+}$$NO _3^{-}$$Cl ^{-}$$SO _4^{2-}$$OH ^{-}$$CH _3COO ^{-}$
$\Lambda _0$$6.2$$7.4$$5.0$$35.0$$7.2$$7.6$$16.0$$19.9$$4.1$

For different combinations of titrates and titrants given in List-$I$,the graphs of 'conductance' versus 'volume of titrant' are given in List-$II$.
List-$I$List-$II$
$(P)$ Titrate: $KCl$,Titrant: $AgNO _3$$(1)$ Graph showing initial decrease then increase
$(Q)$ Titrate: $AgNO _3$,Titrant: $KCl$$(2)$ Graph showing sharp decrease then sharp increase
$(R)$ Titrate: $NaOH$,Titrant: $HCl$$(3)$ Graph showing slight decrease then increase
$(S)$ Titrate: $NaOH$,Titrant: $CH _3COOH$$(4)$ Graph showing continuous increase
$(5)$ Graph showing decrease then constant

Match each entry in List-$I$ with the appropriate entry in List-$II$ and choose the correct option.

During the estimation of oxalic acid $V/S$ $KMnO_4$,the self-indicator is:

$10.0 \, mL$ of $Na_{2}CO_{3}$ solution is titrated against $0.2 \, M \, HCl$ solution. The following titre values were obtained in $5$ readings.
$4.8 \, mL, 4.9 \, mL, 5.0 \, mL, 5.0 \, mL$ and $5.0 \, mL$
Based on these readings,and convention of titrimetric estimation,the concentration of $Na_{2}CO_{3}$ solution is .... $mM$.
(Round off to the nearest integer)

$20 \, mL$ of $0.02 \, M$ hypo solution is used for the titration of $10 \, mL$ of copper sulphate solution,in the presence of excess of $KI$ using starch as an indicator. The molarity of $Cu^{2+}$ is found to be $\times 10^{-2} \, M$ [nearest integer]. Given: $2 Cu^{2+} + 4 I^{-} \rightarrow Cu_{2}I_{2} + I_{2}$ and $I_{2} + 2 S_{2}O_{3}^{2-} \rightarrow 2 I^{-} + S_{4}O_{6}^{2-}$.

Which of the graphs shown below would best represent the change in conductance $(G_{sol})$ when a solution containing $0.1 \, M$ each of $HCl$ and $HCN$ is titrated with $0.1 \, M$ $NaOH$ solution?

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