For the allotropic change represented by the equation $C(\text{diamond}) \to C(\text{graphite})$,the enthalpy change is $\Delta H = -1.89 \ kJ$. If $6 \ g$ of diamond and $6 \ g$ of graphite are separately burnt to yield carbon dioxide,the heat liberated in the first case is:

Match the following allotropes of carbon with their standard enthalpy of formation $(\Delta_f H^{\Theta})$:

Allotrope	$\Delta_f H^{\Theta}$
$i$. Graphite	$b$. $0 \ kJ/mol$
$ii$. Diamond	$c$. $1.90 \ kJ/mol$
$iii$. Fullerene	$a$. $38.1 \ kJ/mol$

$H_2 + Cl_2 \longrightarrow 2HCl$ ; $\Delta H = -x \ kJ$
$NaCl + H_2SO_4 \longrightarrow NaHSO_4 + HCl$ ; $\Delta H = -y \ kJ$
$2H_2O + 2Cl_2 \longrightarrow 4HCl + O_2$ ; $\Delta H = -z \ kJ$
From the above equations,the value of $\Delta H_f$ of $HCl$ is:

Diborane is formed from the elements as shown in equation $(i)$:
$2 B_{(s)} + 3 H_{2(g)} \longrightarrow B_2H_{6(g)} \dots (i)$
Given that:
$H_2O_{(l)} \longrightarrow H_2O_{(g)}, \quad \Delta H_1^{\circ} = 44 \, kJ$
$2 B_{(s)} + \frac{3}{2} O_{2(g)} \longrightarrow B_2O_{3(s)}, \quad \Delta H_2^{\circ} = -1273 \, kJ$
$B_2H_{6(g)} + 3 O_{2(g)} \longrightarrow B_2O_{3(s)} + 3 H_2O_{(g)}, \quad \Delta H_3^{\circ} = -2035 \, kJ$
$H_{2(g)} + \frac{1}{2} O_{2(g)} \longrightarrow H_2O_{(l)}, \quad \Delta H_4^{\circ} = -286 \, kJ$
The $\Delta H^{\circ}$ for the reaction $(i)$ is $..... \, kJ$.

At $1 \ bar$ and $298 \ K$,the standard molar enthalpy of formation of which substance is zero?

Given the thermochemical reactions:
$C(\text{graphite}) + \frac{1}{2} O_{2(g)} \to CO_{(g)}; \Delta H = -110.5 \ kJ$
$CO_{(g)} + \frac{1}{2} O_{2(g)} \to CO_{2(g)}; \Delta H = -283.2 \ kJ$
Calculate the heat of reaction for $C(\text{graphite}) + O_{2(g)} \to CO_{2(g)}$ in $kJ$.