For the electrochemical cell $M \mid M^{2+} \parallel X \mid X^{2-}$,if $E^{\circ}_{(M^{2+} / M)} = 0.46 \ V$ and $E^{\circ}_{(X / X^{2-})} = 0.34 \ V$,which of the following is correct?

What happens to the oxidation number of $Mn$ during the operation of a dry cell?

The standard reduction potential data at $25^{\circ} C$ is given below.
$E^{\circ}(Fe^{3+}, Fe^{2+}) = +0.77 \ V$
$E^{\circ}(Fe^{2+}, Fe) = -0.44 \ V$
$E^{\circ}(Cu^{2+}, Cu) = +0.34 \ V$
$E^{\circ}(Cu^{+}, Cu) = +0.52 \ V$
$E^{\circ}(O_{2(g)} + 4H^{+} + 4e^{-} \rightarrow 2H_{2}O) = +1.23 \ V$
$E^{\circ}(O_{2(g)} + 2H_{2}O + 4e^{-} \rightarrow 4OH^{-}) = +0.40 \ V$
$E^{\circ}(Cr^{3+}, Cr) = -0.74 \ V$
$E^{\circ}(Cr^{2+}, Cr) = -0.91 \ V$
Match $E^{\circ}$ of the redox pair in List-$I$ with the values given in List-$II$ and select the correct answer using the code given below the lists:

List-$I$	List-$II$
$P. \ E^{\circ}(Fe^{3+}, Fe)$	$1. \ -0.18 \ V$
$Q. \ E^{\circ}(4H_{2}O \rightleftharpoons 4H^{+} + 4OH^{-})$	$2. \ -0.4 \ V$
$R. \ E^{\circ}(Cu^{2+} + Cu \rightarrow 2Cu^{+})$	$3. \ -0.04 \ V$
$S. \ E^{\circ}(Cr^{3+}, Cr^{2+})$	$4. \ -0.83 \ V$

Codes: $P \quad Q \quad R \quad S$

$A$ concentrated solution of $KNO_3$ is used in the preparation of a salt bridge because:

An electrochemical cell can behave like an electrolytic cell when . . . . . . .

During the charging of a lead storage battery,the reaction at the anode is: