For the reaction $PCl_{5(g)} \rightleftharpoons PCl_{3(g)} + Cl_{2(g)}$ at equilibrium,the partial pressures of $PCl_5, PCl_3$ and $Cl_2$ are $2 \ atm, 4 \ atm$ and $4 \ atm$ respectively. The value of $K_C$ at $27^{\circ}C$ is (approx):-

  • A
    $\frac{1}{3} \ mol \ L^{-1}$
  • B
    $3 \ mol \ L^{-1}$
  • C
    $\frac{2}{3} \ mol \ L^{-1}$
  • D
    $\frac{1}{2} \ mol \ L^{-1}$

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For the decomposition reaction $N_2O_4 \rightleftharpoons 2NO_2$ at constant temperature,the equilibrium constant is given by $K_p = \frac{4x^2P}{1 - x^2}$,where $P$ is the total pressure and $x$ is the degree of dissociation. Which of the following statements is correct?

$A$ mixture of $1 \ mol$ of $H_2O$ and $1 \ mol$ of $CO$ is taken in a $10 \ L$ container and heated to $725 \ K$. At equilibrium,$40\%$ of water reacts with carbon monoxide according to the equation:
$CO_{(g)} + H_2O_{(g)} \rightleftharpoons CO_{2(g)} + H_{2(g)}$
The equilibrium constant $K_C \times 10^2$ for the reaction is $.......$ (Nearest integer).

For the reactions:
$2NO + O_2 \rightleftharpoons 2NO_2$; $K_1$
$4NO + 2Cl_2 \rightleftharpoons 4NOCl$; $K_2$
$NO_2 + \frac{1}{2}Cl_2 \rightleftharpoons NOCl + \frac{1}{2}O_2$; $K_3$
Where $K_1, K_2, K_3$ are equilibrium constants,then $K_3^2$ is equal to:

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For the reaction,$C_{(s)} + CO_{2(g)} \rightleftharpoons 2CO_{(g)}$,the partial pressures of $CO_2$ and $CO$ are $2.0 \ atm$ and $4.0 \ atm$,respectively,at equilibrium. The $K_p$ of the reaction is

Pure $PCl_5$ is introduced into an evacuated chamber and comes to equilibrium at $247\, ^oC$ and $2.0\ atm$. The equilibrium gaseous mixture contains $40\%$ chlorine by volume. Calculate $K_p$ at $247\, ^oC$ for the reaction $PCl_{5(g)} \rightleftharpoons PCl_{3(g)} + Cl_{2(g)}$ in $atm$.

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