For the reaction at $25\,^oC$,${N_2O_4}_{(g)} \rightleftharpoons 2NO_{2_{(g)}}$,if $\Delta G_f^o$ for $N_2O_4$ and $NO_2$ are $23.49 \, KCal$ and $12.39 \, KCal$ respectively,then $K_p$ for the reaction is: (in $, atm$)

  • A
    $0.78$
  • B
    $0.6$
  • C
    $0.1132$
  • D
    $0.0566$

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At $320 \ K,$ a gas $A_2$ is $20 \%$ dissociated to $A_{(g)}.$ The standard free energy change at $320 \ K$ and $1 \ atm$ in $J \ mol^{-1}$ is approximately $(R = 8.314 \ J \ K^{-1} \ mol^{-1}; \ \ln \ 2 = 0.693; \ \ln \ 3 = 1.098).$

For a certain reaction at $300 \ K$,$K=10$,then $\Delta G^{\circ}$ for the same reaction is . . . . . . $\times 10^{-1} \ kJ \ mol^{-1}$. (Given $R=8.314 \ J \ K^{-1} \ mol^{-1}$)

For the reaction,$2 NH_{3(g)} + CO_{2(g)} \rightleftharpoons NH_2CONH_{2(aq)} + H_2O_{(l)}$,find the value of the equilibrium constant at $295 \ K$. Given,the standard Gibbs energy change at the given temperature is $13.9 \ kJ \ mol^{-1}$.

At $60^{\circ} C$,dinitrogen tetroxide is $50 \%$ dissociated. Find its standard free energy change at this temperature and $1 \ atm$. [ Given: $\log 1.33 = 0.1239 ]$

Calculate the standard Gibbs free energy change $\Delta G^o$ at $298 \ K$ for the conversion of oxygen to ozone,given by the reaction: $\frac{3}{2} O_{2(g)} \rightleftharpoons O_{3(g)}$. The equilibrium constant $K_p$ for this conversion is $3 \times 10^{-29}$.

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