For which of the following graphs is the intersection (y-intercept) zero?

In a first order reaction,the concentration of the reactant decreases from $0.6 \ M$ to $0.3 \ M$ in $15 \ min$. The time taken for the concentration to change from $0.1 \ M$ to $0.025 \ M$ in minutes is

The half-life of a first-order reaction $X \longrightarrow Y + Z$ is $3 \ minutes$. What is the time required to reduce the concentration of $X$ by $90 \%$ of its initial concentration?

For a first order reaction $A \rightarrow B$,the rate constant,$k = 5.5 \times 10^{-14} \, s^{-1}$. The time required for $67 \, \%$ completion of reaction is $x \times 10^{-1}$ times the half life of reaction. The value of $x$ is $....$ (Nearest integer)

In a first order reaction,the concentration of reactant decreases from $800 \ mol/dm^3$ to $50 \ mol/dm^3$ in $2 \times 10^2 \ s$. The rate constant of the reaction in $s^{-1}$ is:

$A_{(g)} \rightarrow 2B_{(g)}$. Initially,$2 \ mol$ of $A$ are taken in a $5 \ L$ vessel. After $20 \ min$,$[A]_t = \frac{[B]_t}{2}$. Find the half-life time of $A$ in the first-order reaction in $\min$.