For which of the following species,Bohr's theory is not applicable?

Typical electronic energy gaps in molecules are about $1.0 \ eV$. In terms of temperature,the gap is closest to

The binding energy of an $e^-$ in the ground state of a hydrogen atom is $13.6 \ eV$. The energy required to remove an electron from the ground state of a $He^+$ ion is:

What is the work function of the metal if the light of wavelength $4000 \, \mathring{A}$ generates photoelectrons of velocity $6 \times 10^5 \, ms^{-1}$ from it? ............. $eV$ (Mass of electron $= 9 \times 10^{-31} \, kg$; Velocity of light $= 3 \times 10^8 \, ms^{-1}$; Planck's constant $= 6.626 \times 10^{-34} \, Js$; Charge of electron $= 1.6 \times 10^{-19} \, C \, eV^{-1}$)

The frequency of the first line of the Paschen series in the spectrum of the $Be^{+3}$ ion is:

As an electron moves away from the nucleus,its energy: