For which one of the following equations is $\Delta H_{react}^o$ equal to $\Delta H_f^o$ for the product?

Given that $:$
$2 C_{(s)} + 2 O_{2_{(g)}} \rightarrow 2 CO_{2_{(g)}} ; \Delta H = -787 \ kJ$
$H_{2_{(g)}} + \frac{1}{2} O_{2_{(g)}} \rightarrow H_2 O_{(l)} ; \Delta H = -286 \ kJ$
$C_2 H_{2_{(g)}} + \frac{5}{2} O_{2_{(g)}} \rightarrow 2 CO_{2_{(g)}} + H_2 O_{(l)} ; \Delta H = -1301 \ kJ$
The heat of formation of acetylene will be $:-$

Identify the $INVALID$ equation.

Given: $S + \frac{3}{2} O_2 \to SO_3 + 2x \ \text{kcal}$,$\Delta H = -2x \ \text{kcal}$ and $SO_2 + \frac{1}{2} O_2 \to SO_3 + y \ \text{kcal}$,$\Delta H = -y \ \text{kcal}$. Find the heat of formation of $SO_2$.

Calculate the standard heat of formation of carbon disulphide $(l)$,given that the standard heat of combustion of carbon $(s)$,sulphur $(s)$ and carbon disulphide $(l)$ are $-393.3, -293.72$ and $-1108.76 \text{ kJ mol}^{-1}$ respectively.

For the reaction,$2 H_{2(g)} + O_{2(g)} \longrightarrow 2 H_{2}O_{(g)}$,$\Delta H^{\circ} = -573.2 \ kJ$. The heat of decomposition of water per mole is