Give the correct order of initials $T$ or $F$ for following statements. Use $T$ if statement is true and $F$ if it is false.
$(i)$ In Goldschmidt thermite process,aluminium acts as a reducing agent.
$(ii)$ $Mg$ is extracted by electrolysis of aqueous solution of $MgCl_2$.
$(iii)$ Extraction of $Pb$ is possible by carbon reduction method.
$(iv)$ Red Bauxite is purified by Serpeck's process.

To obtain steel entirely free from sulphur and phosphorus,the process used is

Addition of high proportions of manganese makes steel useful in making rails of rail-roads because manganese

List-$I$ contains different compounds formed during the extraction of metal $(M)$ in List-$II$. Match the compounds in List-$I$ with the corresponding metal and process in List-$II$.

List-$I$	List-$II$
$(P). [M(CN)_2]^-$	$(1). Ni$ (during refining of metal)
$(Q). [M(CO)_4]$	$(2). Ti$ (during refining of metal)
$(R). MI_4$	$(3). Pb$ (during roasting of ore)
$(S). MO$	$(4). Ag$ (during leaching of ore)

Match List-$I$ with List-$II$ and select the correct answer using the codes given below the list.

List-$I$	List-$II$
$1. Ti$	$A. \text{Bauxite}$
$2. Si$	$B. \text{Cerussite}$
$3. Al$	$C. \text{Van-Arkel method}$
$4. Pb$	$D. \text{Zone refining}$

Explain the following:
$(a)$ $CO_2$ is a better reducing agent below $710 \ K$ whereas $CO$ is a better reducing agent above $710 \ K$.
$(b)$ Generally,sulphide ores are converted into oxides before reduction.
$(c)$ Silica $(SiO_2)$ is added to the sulphide ore of copper in the reverberatory furnace.
$(d)$ Carbon and hydrogen are not used as reducing agents at high temperatures for certain metals.
$(e)$ Vapour phase refining method is used for the purification of $Ti$.