Given below are two statements: $R = 8.314 \text{ J K}^{-1} \text{ mol}^{-1}$ and $1 \text{ cal} = 4.2 \text{ J}$.
Statement $I$: When $E_a = 12.6 \text{ kcal/mol}$, the room temperature rate constant is doubled by a $10 \text{ }^\circ\text{C}$ increase in temperature ($298 \text{ K}$ to $308 \text{ K}$).
Statement $II$: For a first-order reaction $A \to B$, the graph of half-life $(t_{1/2})$ versus initial concentration $[A]_o$ is a straight line passing through the origin.
In the light of the above statements, choose the correct answer from the options given below:

  • A
    Both Statement $I$ and Statement $II$ are true
  • B
    Both Statement $I$ and Statement $II$ are false
  • C
    Statement $I$ is true but Statement $II$ is false
  • D
    Statement $I$ is false but Statement $II$ is true

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For the following parallel chain reaction,what will be the value of the overall half-life of $A$ in minutes?
Given that $\frac{[B]_t}{[C]_t} = \frac{16}{9}$
$A \xrightarrow{k_1 = 2 \times 10^{-3} \ s^{-1}} 4B$
$A \xrightarrow{k_2} C$

Match the column $I$ with column $II$ :
$a$. Rate constant for first order reaction$i$. $mol \ lit^{-1} \sec^{-1}$
$b$. Molarity$ii$. $\frac{k \times 1000}{M}$
$c$. Rate constant for zero order reaction$iii$. $second^{-1}$
$d$. Limiting molar conductivity$iv$. $\frac{\text{moles of solute}}{\text{Volume of solution (lit)}}$

Write equations of the following:
$(i)$ The integrated rate equation for a zero-order reaction.
$(ii)$ The integrated rate equation for a first-order reaction.

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