Given below are two statements:
Statement-$I$ : The number of paramagnetic species among $[CoF_6]^{3-}$, $[TiF_6]^{3-}$, $V_2O_5$ and $[Fe(CN)_6]^{3-}$ is $3$.
Statement-$II$ : $K_4[Fe(CN)_6] < K_3[Fe(CN)_6] < [Fe(H_2O)_6]SO_4 \cdot H_2O < [Fe(H_2O)_6]Cl_3$ is the correct order in terms of number of unpaired electron$(s)$ in the complexes.
In the light of the above statements, choose the correct answer from the options given below.

  • A
    Both statement-$I$ and statement-$II$ are true
  • B
    Both statement-$I$ and statement-$II$ are false
  • C
    Statement-$I$ is true but statement-$II$ is false
  • D
    Statement-$I$ is false but statement-$II$ is true

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$(i)$ $K_4[Fe(CN)_6]$
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Identify the homoleptic complexes with an odd number of $d$ electrons in the central metal ion.
$(A) \ [FeO_4]^{2-}$
$(B) \ [Fe(CN)_6]^{3-}$
$(C) \ [Fe(CN)_5 NO]^{2-}$
$(D) \ [CoCl_4]^{2-}$
$(E) \ [Co(H_2O)_3 F_3]$
Choose the correct answer from the options given below $:$

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