How do you perform the purification of the following?
$(i)$ The boiling point of liquid $X$ is $450 \ K$ and it decomposes at $400 \ K$ temperature.
$(ii)$ Mixture of $60 \% \ \text{Camphor}$ and $40 \% \ BaSO_4$.

Match Column-$I$ and Column-$II$ with the correct relation:

Column-$I$	Column-$II$
$(i)$ Aniline + chloroform	$(p)$ Steam distillation
$(ii)$ Aqueous solution of compound	$(q)$ Fractional distillation
$(iii)$ Mixture of liquids with small difference in boiling point	$(r)$ Differential extraction
$(iv)$ Purification of aniline	$(s)$ Simple distillation

Explain the principle of paper chromatography.

Identify the purification technique for the following mixtures:
$(i)$ Chloroform and aniline
$(ii)$ Impure acetone
$(iii)$ Impure aniline
$(iv)$ Chlorobenzene and bromobenzene

In the given $TLC$ plate,the distances of spots $A$ and $B$ from the base line are $4 \ cm$ and $6 \ cm$,respectively. The distance moved by the solvent front from the base line is $8 \ cm$. If the $R_f$ value of $B$ is $x \times 10^{-1}$ times that of $A$,find the value of $x$.

$X$ and $Y$ have $R_f$ values of $0.75$ and $0.25$ respectively. In column chromatography,which component is obtained first?