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Give reactions of carboxylic acids in which $C-OH$ bond breaks. $OR$ Give methods of preparation for $(a)$ anhydride $(b)$ ester $(c)$ acid chloride and $(d)$ amide from carboxylic acids.

$CH_3MgBr$ (excess) + $EtO-C(=O)-OEt$ $\xrightarrow{(2) H^{+}}$ $(A)$; Product $(A)$ is:

Acetyl chloride cannot be obtained by treating acetic acid with

Acetic anhydride reacts with an excess of ammonia to form:

When $C_6H_5Z$ undergoes electrophilic substitution,the major product obtained is the meta-isomer. Therefore,the group $Z$ is:

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