Identify the correct decreasing order of wavelength of light absorbed for the following complex ions:
$I. [Co(H_2O)_6]^{3+}$
$II. [Co(CN)_6]^{3-}$
$III. [CoI_6]^{3-}$
$IV. [Co(en)_3]^{3+}$

  • A
    $III > I > IV > II$
  • B
    $II > IV > I > III$
  • C
    $III > I > II > IV$
  • D
    $I > III > IV > II$

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$[Pd(F)(Cl)(Br)(I)]^{2-}$ has $n$ number of geometrical isomers. Then,the spin-only magnetic moment and crystal field stabilisation energy $[CFSE]$ of $[Fe(CN)_6]^{n-6}$ are
[Note : Ignore the pairing energy]

The correct sequence of ligands in the order of decreasing field strength is:

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Match List-$I$ with List-$II$. Choose the correct answer from the options given below:
| List-$I$ (Complex ion) | List-$II$ (Electronic Configuration) |
| :--- | :--- |
| $A. [Cr(H_2O)_6]^{3+}$ | $I. t_{2g}^2 e_g^0$ |
| $B. [Fe(H_2O)_6]^{3+}$ | $II. t_{2g}^3 e_g^0$ |
| $C. [Ni(H_2O)_6]^{2+}$ | $III. t_{2g}^3 e_g^2$ |
| $D. [V(H_2O)_6]^{3+}$ | $IV. t_{2g}^6 e_g^2$ |

Correct increasing order for the wavelength of absorption in the visible region for the complexes of $Co^{3+}$ is :

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