Identify the correct statement from the following regarding a chemical reaction.

  • A
    The entropy always increases.
  • B
    The change in entropy along with a suitable change in enthalpy decides the spontaneity of the reaction.
  • C
    The enthalpy always decreases.
  • D
    Both the enthalpy and the entropy remain constant.

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For the reaction at $300 \, K$,$A_{(g)} + B_{(g)} \to C_{(g)}$,given $\Delta U = -3 \, kcal$ and $\Delta S = -10 \, cal/K$. The value of $\Delta G$ will be $...... \, cal$.

When $2.0 \ g$ of sucrose is oxidized to form $CO_{2(g)}$ and $H_2O(\ell)$,the internal energy changes by $-24 \ kJ$. Calculate the value of $\Delta H$ at $298 \ K$ in $kJ \ mol^{-1}$. (Molar mass of sucrose $= 342 \ g \ mol^{-1}$)

Calculate the work done during the combustion of $0.138 \ kg$ of ethanol,$(C_2H_5OH_{(l)})$ at $300 \ K$. Given: $R = 8.314 \ J \ K^{-1} \ mol^{-1}$ and molar mass of ethanol $= 46 \ g \ mol^{-1}$. (in $J$)

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The combustion of one mole of benzene takes place at $298 \, K$ and $1 \, atm$. After combustion,$CO_{2(g)}$ and $H_2O_{(l)}$ are produced and $3267.0 \, kJ$ of heat is liberated. Calculate the standard enthalpy of formation,$\Delta_f H^{\ominus}$ of benzene. Standard enthalpies of formation of $CO_{2(g)}$ and $H_2O_{(l)}$ are $-393.5 \, kJ \, mol^{-1}$ and $-285.83 \, kJ \, mol^{-1}$ respectively.

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