Identify the end product $(B)$ of the following sequence of reactions:
Phenol $\xrightarrow[100^{\circ}C]{\text{conc. } H_2SO_4} A$ $\xrightarrow{Br_2/H_2O \text{ (excess)}} B$

  • A
    $2,6-$dibromo$-4-$sulfophenol
  • B
    $2,4-$dibromophenol
  • C
    $2,4,6-$tribromophenol
  • D
    $2-$bromo$-4-$sulfophenol

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Which one of the following compounds is most acidic?

Given below are two statements: One is labelled as $Assertion$ $A$ and the other is labelled as $Reason$ $R$:
Assertion $A$: $pK_a$ value of phenol is $10.0$ while that of ethanol is $15.9$.
Reason $R$: Ethanol is a stronger acid than phenol.
In the light of the above statements,choose the correct answer from the options given below:

Rank the following compounds in order of decreasing acid strength (most acidic $\to$ least acidic):

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Which compound has the highest value of $pK_{a}$?

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