Identify the incorrect match in the following reactions:

  • A
    Benzene diazonium salt + $Cu_2X_2/HX \rightarrow \text{ESR}$
  • B
    Toluene + $X_2/Fe \text{ (dark)} \rightarrow \text{ESR}$
  • C
    $p$-Nitroethylbenzene + $Cl_2/AlCl_3 \rightarrow \text{ESR}$
  • D
    $p$-Hydroxybenzyl alcohol + $HCl \text{ (heat)} \rightarrow \text{NSR}$

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Assertion : $4-$Nitrochlorobenzene undergoes nucleophilic substitution more readily than chlorobenzene.
Reason : Chlorobenzene undergoes nucleophilic substitution by elimination-addition mechanism while $4-$nitrochlorobenzene undergoes nucleophilic substitution by addition-elimination mechanism.

In which reaction does nitrobenzene give $o$- and $p$-substituted products?

Which of the following possesses the highest melting point?

The product obtained after the nitration of nitrobenzene is:

Match the reactants in Column-$I$ with their products in Column-$II$.
Column-$I$ (Reactants)Column-$II$ (Products)
$(A)$ $p$-Nitrochlorobenzene $\xrightarrow[(ii) H^+]{(i) NaOH, 443 \ K}$$(i)$ Phenol
$(B)$ Chlorobenzene $\xrightarrow[(ii) H^+]{(i) NaOH, 623 \ K, 300 \ atm}$$(ii)$ $2,4,6$-Trinitrophenol
$(C)$ $2,4$-Dinitrochlorobenzene $\xrightarrow[(ii) H^+]{(i) NaOH, 368 \ K}$$(iii)$ $2,4$-Dinitrophenol
$(D)$ $2,4,6$-Trinitrochlorobenzene $\xrightarrow{Warm \ H_2O}$$(iv)$ $p$-Nitrophenol

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