Identify the incorrect statement.

  • A
    An octadecapeptide contains $18$ amino acid residues and $17$ peptide bonds.
  • B
    Addition of an inert gas into a system in thermodynamic equilibrium for the dissociation of $PCl_5$ at constant volume does not shift the equilibrium.
  • C
    When gold dissolves in aqua regia,the complex formed is chloroauric acid.
  • D
    If the $pH$ value of a solution is to be decreased from $5$ to $3$,the hydrogen ion concentration must be increased $100$ times the initial value.

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For the reaction $PCl_{5(g)} \rightleftharpoons PCl_{3(g)} + Cl_{2(g)}$,the value of $K_c$ is $0.04$ at $250 \ ^oC$ in a $3 \ L$ vessel. If the concentration of $Cl_2$ at equilibrium is $0.15 \ M$,then the initial moles of $PCl_5$ will be ...........

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If the reaction is started with $NH_4COONH_{2(s)}$ and the equilibrium mixture has a total pressure of $3 \ atm$,then the $K_P$ for the reaction $NH_4COONH_{2(s)} \rightleftharpoons 2NH_{3(g)} + CO_{2(g)}$ is ..... $atm^3$.

If the equilibrium constant $K_c = 0.04$,how many moles/liter of $PCl_5$ are required to obtain $0.1$ mole of $Cl_2$?

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For the reaction $2P_{(g)} + Q_{(g)} \rightleftharpoons R_{(g)} + S_{(g)}$; $K_C = 10^{12}$. If the initial moles of $P, Q, R, S$ are $2, 1, 7$ and $3$ moles respectively in a $1 \ L$ vessel,find the equilibrium concentration of $P$.

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Consider the following reversible first-order reaction of $X$ at an initial concentration $[X]_{0}$. The values of the rate constants are $K_{f} = 2 \ s^{-1}$ and $K_{b} = 1 \ s^{-1}$.
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Which of the following plots correctly represents the concentration of $X$ and $Y$ as a function of time?

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