Identify the product when chlorobenzene is he | vedclass

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Question

(C) Chlorobenzene undergoes electrophilic aromatic substitution when treated with a nitrating mixture (concentrated $HNO_3$ and concentrated $H_2SO_4$

Vedclass · Accepted Answer

Mixture of $1-$chloro$-2-$nitrobenzene and $1-$chloro$-4-$nitrobenzene

Vedclass · Answer

(C) Chlorobenzene undergoes electrophilic aromatic substitution when treated with a nitrating mixture (concentrated $HNO_3$ and concentrated $H_2SO_4$).Since the chlorine atom is ortho/para-directing due to the resonance effect,the nitration occurs at both the ortho and para positions.Therefore,the reaction yields a mixture of $1-$chloro$-2-$nitrobenzene (ortho-isomer) and $1-$chloro$-4-$nitrobenzene (para-isomer).

Identify the product when chlorobenzene is heated with nitrating mixture.

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