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(D) The given complexes are $[Cr(H_2O)_6]Cl_3$ and $[Cr(H_2O)_5Cl]Cl_2 \cdot H_2O$. In these complexes,the water molecule $(H_2O)$ acts as a ligand in

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Solvate isomerism

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(D) The given complexes are $[Cr(H_2O)_6]Cl_3$ and $[Cr(H_2O)_5Cl]Cl_2 \cdot H_2O$. In these complexes,the water molecule $(H_2O)$ acts as a ligand in the first complex,while in the second complex,one $H_2O$ molecule is present outside the coordination sphere as a solvent molecule. This type of isomerism,where the solvent molecule (usually water) exchanges its position between the coordination sphere and the lattice,is known as solvate isomerism (also called hydrate isomerism).

Identify the type of isomerism exhibited by the complex compounds: $[Cr(H_2O)_6]Cl_3$ and $[Cr(H_2O)_5Cl]Cl_2 \cdot H_2O$.

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