If a chemical reaction is accompanied by the evolution of heat,it is

  • A
    Catalytic
  • B
    Photochemical
  • C
    Endothermic
  • D
    Exothermic

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$A$ given mass of gas expands reversibly from the state $A$ to the state $B$ by three paths $1, 2$ and $3$ as shown in the figure. If $w_1, w_2$ and $w_3$ respectively be the work done by the gas along three paths then:

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