If a solute associates in a solvent, its experimentally calculated molar mass using the boiling point elevation method will be

$2 \,g$ of benzoic acid $(C_{6}H_{5}COOH)$ dissolved in $25 \,g$ of benzene shows a depression in freezing point equal to $1.62 \,K$. The molal depression constant for benzene is $4.9 \,K \,kg \,mol^{-1}$. What is the percentage association of the acid if it forms a dimer in the solution?

The freezing point of benzene decreases by $0.45 ^\circ C$ when $0.2 \ g$ of acetic acid is added to $20 \ g$ of benzene. If acetic acid associates to form a dimer in benzene,the percentage association of acetic acid in benzene will be .......... $\%$
$(K_f \text{ for benzene} = 5.12 \ K \ kg \ mol^{-1})$

Pure benzene freezes at $5.3^oC$. $A$ solution of $0.223 \ g$ of $C_6H_5CH_2COOH$ in $4.49 \ g$ of benzene freezes at $4.47^oC$. Given $K_f = 5.12 \ K \ kg/mol$,what can be concluded from this?

The values of observed and calculated molecular mass of silver nitrate are $92.64$ and $170$ respectively. The degree of dissociation of silver nitrate is ........ $\%$.

The van't Hoff factor $i$ for a compound which undergoes dissociation in one solvent and association in other solvent is respectively